A facile access to rac ansa-lanthanocene alkyl complexes with an ether-bridged indenyl ligand and crystal structure of rac-[O(CH2CH2C9H6),]YCH2SiMe3

Citation
Ct. Qian et al., A facile access to rac ansa-lanthanocene alkyl complexes with an ether-bridged indenyl ligand and crystal structure of rac-[O(CH2CH2C9H6),]YCH2SiMe3, J CHEM S DA, (4), 1999, pp. 519-520
Citations number
11
Categorie Soggetti
Inorganic & Nuclear Chemistry
Journal title
JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS
ISSN journal
03009246 → ACNP
Issue
4
Year of publication
1999
Pages
519 - 520
Database
ISI
SICI code
0300-9246(19990221):4<519:AFATRA>2.0.ZU;2-0
Abstract
Pure rac ansa-lanthanocene alkyl complexes [O(CH2CH2C9H6)(2)]LnCH(2)SiMe(3) (Ln = Y 1, Lu 2) are stereoselectively formed dictated by the nonbonded in teractions between the six-membered portion of the indenyl moiety and the a lkyl group.