Helicity of the SmC alpha* phase and its variations in a thiobenzoate series

Citation
V. Laux et al., Helicity of the SmC alpha* phase and its variations in a thiobenzoate series, LIQ CRYST, 26(3), 1999, pp. 361-373
Citations number
17
Categorie Soggetti
Physical Chemistry/Chemical Physics
Journal title
LIQUID CRYSTALS
ISSN journal
02678292 → ACNP
Volume
26
Issue
3
Year of publication
1999
Pages
361 - 373
Database
ISI
SICI code
0267-8292(199903)26:3<361:HOTSAP>2.0.ZU;2-O
Abstract
We have studied by optical means a thiobenzoate series exhibiting SmCA*, Sm C*, SmCFI*, and SmCalpha* phases. We have made pitch measurements on the Sm CA* and SmC* phases using the Grandjean-Cano method. Observing free surface drops in the SmCalpha* phase, we found periodic ellipticity fringes, due t o a helical structure, and measured their optical period versus temperature ; this can reach very small as well as significant values. It does not exhi bit a single evolution and appears incoherent at first sight, but always fo llows one part of a general behaviour, depending on the thermal history of the sample. Lastly we compare experimental results with one of the structur al models proposed for the SmCalpha* phase.