Hp. Saha et D. Lin, THEORETICAL-STUDY OF THE VALENCE AND CORE PHOTOIONIZATION OF A 3-ELECTRON SYSTEM FROM LITHIUM TO NEON, Journal of physics. B, Atomic molecular and optical physics, 30(7), 1997, pp. 1651-1667
The multiconfiguration Hartree-Fock (MCHF) method for continuum wavefu
nctions is used to study the photoionization of lithium and ions of it
s isoelectronic sequence for photon energies from 0.1 to 250 Ryd. Elec
tron correlation and polarization effects in the initial and final sta
tes and relaxation and correlation in the final ionic stales, which ar
e found to be very important in the valence- and K-shell partial photo
ionization cross sections, have been taken into account accurately in
an ab initio manner through the configuration interaction procedure. T
he present results are compared with available experimental measuremen
ts and accurate theoretical data for a limited energy range and are fo
und to be in good agreement.