The ultrafast nonradiative bimolecular recombination of charge carriers was
investigated in amorphous and microcrystalline silicon. The photoelectric
method based on measurement of extraction time of the charge carrier reserv
oir in the space-charge-limited photocurrent mode was used. A series of mod
els (Auger, diffusion-controlled, charge-carrier-fluctuation dominated) wer
e experimentally tested but were not able to explain all features of bimole
cular recombination in a-Si:H. The model of diffusion limited recombination
taking into account the intrinsic random potential seems most suitable for
a description of the observed suppressed bimolecular recombination.