Via ferromagnetic resonance both the magnetic anisotropy energy (MAE) and t
he spectroscopic splitting tensor (g tensor) for a bcc Fe-2/V-5(001) superl
attice are measured independently. The theoretically proposed proportionali
ty between the anisotropy of the orbital moment mu(L) and the MAE is quanti
tatively checked and its limitations are discussed. From layer-resolved fir
st-principles calculations we find a reduced spin moment mu(S) = 1.62 mu(B)
for Fe and mu(S)(V) = -0.67 mu(B) in the first V layer. The g-tensor eleme
nts reveal a 300% enhanced ratio mu(L)/mu(S) = 0.133 in comparison to bulk
Fe. The MAE and the orbital moment anisotropy is found to be unusually smal
l for Fe monolayers.