Thin films of aluminum nitride (AlN) have been grown on (0001) oriented sap
phire (alpha-Al2O3) substrates through the use of an externally applied ele
ctric field. By applying an electric field with an appropriate electrode ma
terial, at elevated temperatures, across Al2O3, a flux of Al3+ cations towa
rd the cathode was induced. The cations arriving at the surface of the Al2O
3 then reacted with a nitrogen gas atmosphere to form a thin epitactic film
of AlN on the Al2O3. (C) 1999 Elsevier Science S.A. All rights reserved.