K3SbSe3, Rb3SbSe3, and Cs3SbSe3 - Synthesis and crystal structure

Authors
Bronger, W Donike, A Schmitz, D
Citation
W. Bronger et al., K3SbSe3, Rb3SbSe3, and Cs3SbSe3 - Synthesis and crystal structure, Z ANORG A C, 625(3), 1999, pp. 435-437
Citations number
13
Categorie Soggetti
Inorganic & Nuclear Chemistry
Journal title
ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE
ISSN journal
00442313 → ACNP
Volume
625
Issue
3
Year of publication
1999
Pages
435 - 437
Database
ISI
SICI code
0044-2313(199903)625:3<435:KRAC-S>2.0.ZU;2-7
Abstract
The compounds K3SbSe3, Rb3SbSe3 and Cs3SbSe3 were synthesized by heating mi xtures of Sb2O3 and an alkali-carbonate in a stream of hydrogen saturated b y selenium in a temperature range between 750 degrees C and 800 degrees C. The compounds crystallize isostructural with Na3AsS3. A comparison of atomi c distances and bond angles with those of the isostructural arsenic and bis muth compounds shows the effect of lone pairs.