Pure rotational spectra of CS

Citation
V. Ahrens et G. Winnewisser, Pure rotational spectra of CS, Z NATURFO A, 54(2), 1999, pp. 131-136
Citations number
18
Categorie Soggetti
Physical Chemistry/Chemical Physics
Journal title
ZEITSCHRIFT FUR NATURFORSCHUNG SECTION A-A JOURNAL OF PHYSICAL SCIENCES
ISSN journal
09320784 → ACNP
Volume
54
Issue
2
Year of publication
1999
Pages
131 - 136
Database
ISI
SICI code
0932-0784(199902)54:2<131:PRSOC>2.0.ZU;2-5
Abstract
The pure rotational spectra of CS and its isotopomers (CS)-C-12-S-33, (CS)- C-12-S-34, (CS)-C-13-S-32, (CS)-C-13-S-33, (CS)-C-13-S-34 including the ver y rare isotopomer (CS)-C-12-S-36 were observed. The rotational spectra incl ude ground and vibrationally excited transitions up to v - 16. The new meas urements have been performed with the Cologne terahertz spectrometer coveri ng the frequency region from 259 to 1075 GHz. These newly observed rotation al transitions together with earlier data were fitted to a Dunham-type Hami ltonian. The obtained isotopically invariant parameters include vibrational and rotational expansion coefficients.