Mc. Greca et al., Evaluation of Pd/alumina catalysts, produced by combustion synthesis, in the ethanol oxidation reaction to acetic acid, APP CATAL A, 179(1-2), 1999, pp. 87-92
Combustion synthesis is a quick, straightforward preparation process to pro
duce homogeneous, very fine, crystalline and unagglomerated multicomponent
oxide ceramic powders, without the intermediate decomposition and/or calcin
ing steps, and was used to prepare a palladium/alumina catalyst oxide precu
rsor. The present work describes the synthesis of the catalyst and compares
its performance, in the acetic acid formation from ethanol oxidation react
ion, with that of the equivalent catalyst synthesized via the usual techniq
ue of an independent support impregnation step.
The phase formation and characteristics of the powder produced (morphology
and grain size) were investigated and are also discussed. Results show that
the combustion synthesis produces solids with specific surface areas 60% h
igher than those obtained by the conventional technique.
The catalytic test results show that the combustion synthesis catalysts hav
e higher activity and acetic acid selectivity, in the ethanol oxidation rea
ction. (C) 1999 Elsevier Science B.V. All rights reserved.