The dynamics of electrons in image-potential states has been studied by mea
ns of time- and energy-resolved two-photon photoemission. The loss of coher
ence in quantum-beat spectroscopy shows directly the influence of pure deph
asing which can be determined also from the difference between the results
of linewidth and decay rate measurements. We present several examples for t
he correlation of decay and dephasing with surface defects and disorder.