Cyclohexylation of naphthalene over USY zeolites

Citation
M. Michvocik et al., Cyclohexylation of naphthalene over USY zeolites, COLL CZECH, 64(1), 1999, pp. 138-148
Citations number
16
Categorie Soggetti
Chemistry
Journal title
COLLECTION OF CZECHOSLOVAK CHEMICAL COMMUNICATIONS
ISSN journal
00100765 → ACNP
Volume
64
Issue
1
Year of publication
1999
Pages
138 - 148
Database
ISI
SICI code
0010-0765(199901)64:1<138:CONOUZ>2.0.ZU;2-J
Abstract
The influence of thermal stabilization of NH4-Y zeolite and modification of USY zeolites with solutions of hydrochloric acid on the cyclohexylation of naphthalene in the liquid phase was studied. Removal of the part of extra- framework aluminium from zeolite structure has a positive effect on both co nversion of naphthalene and amount of dicyclohexylnaphthalenes formed. Modi fication of zeolites leads to an increase in conversion and selectivity of beta-substitution in the naphthalene cyclohexylation.