Excess molar volumes and viscosities of binary liquid mixtures of ethyleneglycol dimethyl ether plus ethylene glycol monomethyl, plus diethylene glycol monomethyl, and plus triethylene glycol monomethyl ethers at 298.15 and308.15 K

Authors
Citation
A. Pal et S. Sharma, Excess molar volumes and viscosities of binary liquid mixtures of ethyleneglycol dimethyl ether plus ethylene glycol monomethyl, plus diethylene glycol monomethyl, and plus triethylene glycol monomethyl ethers at 298.15 and308.15 K, J CHEM EN D, 44(2), 1999, pp. 212-215
Citations number
23
Categorie Soggetti
Chemistry,"Chemical Engineering
Journal title
JOURNAL OF CHEMICAL AND ENGINEERING DATA
ISSN journal
00219568 → ACNP
Volume
44
Issue
2
Year of publication
1999
Pages
212 - 215
Database
ISI
SICI code
0021-9568(199903/04)44:2<212:EMVAVO>2.0.ZU;2-8
Abstract
Excess molar volumes V-m(E), and viscosities eta have been measured as a fu nction of mole fraction for binary liquid mixtures of ethylene glycol dimet hyl ether (1,2-dimethoxyethane), CH3OC2H4OCH3, with diethylene glycol monom ethyl ether (2-(2-methoxyethoxy)ethanol), CH3(OC2H4)(2)OH, and triethylene glycol monomethyl ether (2-[2-(2-methoxyethoxy)ethoxy]ethanol), CH3(OC2H4)( 3)OH, at 298.15 and 308.15 K and at atmospheric pressure. Measurements of v iscosity at 298.15 and 308.15 K and excess molar volume at 308.15 K have al so been made for the mixtures ethylene glycol dimethyl ether + ethylene gly col monomethyl ether (2-methoxyethanol), CH3OC2H4OH, over the whole composi tion range. Density rho of the mixtures have been calculated from the resul ts. All of the systems show negative deviation from a mole fraction average in viscosity. The excess molar volumes for all of the mixtures are negativ e over the entire composition range.