Excess molar volumes and viscosities of binary liquid mixtures of ethyleneglycol dimethyl ether plus ethylene glycol monomethyl, plus diethylene glycol monomethyl, and plus triethylene glycol monomethyl ethers at 298.15 and308.15 K
A. Pal et S. Sharma, Excess molar volumes and viscosities of binary liquid mixtures of ethyleneglycol dimethyl ether plus ethylene glycol monomethyl, plus diethylene glycol monomethyl, and plus triethylene glycol monomethyl ethers at 298.15 and308.15 K, J CHEM EN D, 44(2), 1999, pp. 212-215
Excess molar volumes V-m(E), and viscosities eta have been measured as a fu
nction of mole fraction for binary liquid mixtures of ethylene glycol dimet
hyl ether (1,2-dimethoxyethane), CH3OC2H4OCH3, with diethylene glycol monom
ethyl ether (2-(2-methoxyethoxy)ethanol), CH3(OC2H4)(2)OH, and triethylene
glycol monomethyl ether (2-[2-(2-methoxyethoxy)ethoxy]ethanol), CH3(OC2H4)(
3)OH, at 298.15 and 308.15 K and at atmospheric pressure. Measurements of v
iscosity at 298.15 and 308.15 K and excess molar volume at 308.15 K have al
so been made for the mixtures ethylene glycol dimethyl ether + ethylene gly
col monomethyl ether (2-methoxyethanol), CH3OC2H4OH, over the whole composi
tion range. Density rho of the mixtures have been calculated from the resul
ts. All of the systems show negative deviation from a mole fraction average
in viscosity. The excess molar volumes for all of the mixtures are negativ
e over the entire composition range.