New insights on the reaction of alkyl 3-oxo-4-(triphenylphosphoranylidene)butanoate and aldehydes under concentrated condensation conditions. One-potsynthesis of highly functionalised 6-oxocyclohex-4-ene-1,3-dicarboxylates

Authors
Moorhoff, CM Schneider, DF Winkler, D
Citation
Cm. Moorhoff et al., New insights on the reaction of alkyl 3-oxo-4-(triphenylphosphoranylidene)butanoate and aldehydes under concentrated condensation conditions. One-potsynthesis of highly functionalised 6-oxocyclohex-4-ene-1,3-dicarboxylates, J CHEM R-S, (12), 1998, pp. 763-763A
Citations number
17
Categorie Soggetti
Chemistry
Journal title
JOURNAL OF CHEMICAL RESEARCH-S
ISSN journal
03082342 → ACNP
Issue
12
Year of publication
1998
Pages
763 - 763A
Database
ISI
SICI code
0308-2342(199812):12<763:NIOTRO>2.0.ZU;2-V
Abstract
A general method for the synthesis of substituted cyclohexenones 5 from the condensation of acetoacetate phosphonium ylide 1 and saturated and unsatur ated aldehydes 2, without activation, is described.