The influence of liquid pressures and orifice diameters on the sprayability
of non-Newtonian, waterborne latex coatings, that vary in latex particle s
ize and thickener composition are examined in this study. It is observed th
at the higher the dynamic uniaxial extensional viscosities (DUEVs, eta(e))
of the coatings, the larger the Sauter mean diameters (SMDs) of the spray d
roplets and the broader the droplet size distributions. The shear viscositi
es at high shear rates and the parameter reflecting shear elasticity, the s
torage moduli, at low deformation rates do not correlate with the droplet s
izes and the distributions observed. In addition to these observations, the
Sauter mean diameters of spray droplets decrease with increasing spray pre
ssures and with decreasing orifice diameters; however, with increasing pres
sures, pulsations in the fluid due to turbulence create areas of high and l
ow droplet density.
The relationship of the SMD to orifice diameters using fan nozzles is defin
ed by the relationship:
SMD/d(h) = 5.5 [sigma eta(e)(4)/(rho(A)d(h)(3)Delta P-L(2))](0.25) + 2 [sig
ma rho(L)/(rho(A)d(h)Delta P-L)](0.25).
The experimental results associated with each of these parameters are discu
ssed in the text.