A convenient synthesis of carbonyl chloride fluoride

Authors
Hoe, B Christe, KO
Citation
B. Hoe et Ko. Christe, A convenient synthesis of carbonyl chloride fluoride, J FLUORINE, 94(1), 1999, pp. 107-108
Citations number
14
Categorie Soggetti
Inorganic & Nuclear Chemistry
Journal title
JOURNAL OF FLUORINE CHEMISTRY
ISSN journal
00221139 → ACNP
Volume
94
Issue
1
Year of publication
1999
Pages
107 - 108
Database
ISI
SICI code
0022-1139(19990211)94:1<107:ACSOCC>2.0.ZU;2-N
Abstract
An improved method for the synthesis of COClF under mild conditions is repo rted. Pure COClF can be isolated in essentially quantitative yield from the decomposition of the oxygen-bridged COCl2. SbF5 donor-acceptor adduct at r oom temperature in a dynamic vacuum. (C) 1999 Elsevier Science S.A. All rig hts reserved.