THE STRUCTURE OF THE [FE(CN)(6)](4-) SHALLOW ELECTRON CENTER IN SILVER-CHLORIDE

Authors
BENNEBROEK MT SCHMIDT J EACHUS RS OLM MT
Citation
Mt. Bennebroek et al., THE STRUCTURE OF THE [FE(CN)(6)](4-) SHALLOW ELECTRON CENTER IN SILVER-CHLORIDE, Journal of physics. Condensed matter, 9(15), 1997, pp. 3227-3240
Citations number
22
Categorie Soggetti
Physics, Condensed Matter
Journal title
Journal of physics. Condensed matter → ACNP
ISSN journal
09538984
Volume
9
Issue
15
Year of publication
1997
Pages
3227 - 3240
Database
ISI
SICI code
0953-8984(1997)9:15<3227:TSOT[S>2.0.ZU;2-O
Abstract
The results of an ENDOR study of electrons shallowly trapped at [Fe(CN )(6)](4-) complexes doped in AgCl emulsions reveal that the dopant rep laces a [AgCl6](5-) lattice unit without an additional lowering of the local symmetry and without the association of charge-compensating cat ionic vacancies. Effects of the grain structure seem to interfere in t he interpretation of the results from C-13-enriched [Fe(CN)(6)](4-)-do ped emulsions, for which an ensemble of slightly different electron ce ntres is believed to be observed.