Ds. Boyle et al., Novel approach to the deposition of CdS by chemical bath deposition: the deposition of crystalline thin films of CdS from acidic baths, J MAT CHEM, 9(3), 1999, pp. 725-729
Thin films of cadmium sulfide have been deposited from acidic solutions. Th
e films have been characterised by electronic, photoluminescence (PL) and X
-ray photoelectron( XPS) spectroscopies, scanning and transmission electron
microscopy (SEM and TEM) and powder X-ray diffraction (XRD). The as-deposi
ted polycrystalline CdS films are hexagonal, the crystallinity of the films
is improved by annealing in air at 400 degrees C. The procedure also leads
to a concentration of chloride at the surface of the films. Deposition fro
m acidic baths may open up new simple synthetic routes towards the ternary
cadmium-zinc sulfide system.