Ethene and styrene insertion into the Pd-acyl bond of [Pd(COMe)(P boolean AND N)(solv)]O3SCF3 and its role in the copolymerisation of olefins with carbon monoxide

Authors
Aeby, A Consiglio, G
Citation
A. Aeby et G. Consiglio, Ethene and styrene insertion into the Pd-acyl bond of [Pd(COMe)(P boolean AND N)(solv)]O3SCF3 and its role in the copolymerisation of olefins with carbon monoxide, J CHEM S DA, (5), 1999, pp. 655-656
Citations number
26
Categorie Soggetti
Inorganic & Nuclear Chemistry
Journal title
JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS
ISSN journal
03009246 → ACNP
Issue
5
Year of publication
1999
Pages
655 - 656
Database
ISI
SICI code
0300-9246(19990307):5<655:EASIIT>2.0.ZU;2-N
Abstract
Styrene has higher productivity than ethene during copolymerisation with ca rbon monoxide using [Pd(COCH3)((PN)-N-boolean AND)(solv)]O3SCF3 (where (PN) -N-boolean AND is a phosphanyldihydrooxazole ligand), while ethene, not sty rene, is preferentially enchained during the terpolymerisation probably ref lecting the different reactivity of the two possible alkyl intermediates to ward carbon monoxide insertion.