Enargite Cu3AsS4 belongs to minerals with very low hydrometallurgical extra
ctibility of copper. AN application pretreatment of enargite concentrate in
acid solutions leads to simultaneous dissolution of copper and arsenic and
the final leach liquors solutions have to be treated for the separation of
both elements. The application of alkaline natrium sulphide solutions favo
urs a selective leaching of arsenic and the copper forms solid residues sui
table for pyrometallurgical treatment. The experiments have shown that more
than 90% of arsenic can be extracted from enargite by atmospheric alkaline
leaching at 90 degrees C. An applied mechanical activation enhances the ra
te of arsenic extraction.