Analytical solution of the Yukawa closure of the Ornstein-Zernike equationIII: the one-component case

Citation
L. Blum et Jn. Herrera, Analytical solution of the Yukawa closure of the Ornstein-Zernike equationIII: the one-component case, MOLEC PHYS, 96(5), 1999, pp. 821-826
Citations number
33
Categorie Soggetti
Physical Chemistry/Chemical Physics
Journal title
MOLECULAR PHYSICS
ISSN journal
00268976 → ACNP
Volume
96
Issue
5
Year of publication
1999
Pages
821 - 826
Database
ISI
SICI code
0026-8976(19990310)96:5<821:ASOTYC>2.0.ZU;2-R
Abstract
A new general form of the multi-Yukawa closure of the Ornstein-Zernike equa tion is discussed for the case of one component and two exponentials. This closure is given in terms of a diagonal scaling matrix Gamma. If we are dea ling with a pure fluid then the general form of the closure is 2 pi K-n[X-(n)](2) + z(n)beta((n))[1 + rho Sigma(m) 1/z(n)+z(m) beta((m))] = 0 where beta((m)) is obtained by solving a linear matrix equation [GRAPHICS] where the matrix M-m depends only on z(n) and Gamma((nn)). Explicit expessi ons for the excess thermodynamic functions are also found.