A brief survey is presented, in the historical context, of the development
of physical views on the mechanisms of photoelectron emission from effectiv
e photocathodes. Particular emphasis is placed On the impact of many-body e
xcitations, such as excitons in semiconductors and electronic excitations i
n metal particles and at metal surfaces, on the efficiency of antimony-cesi
um, silver-oxygen-cesium and magnesium-barium photocathodes. We give exampl
es how the quasi-two-dimensional photoelectron emission from subsurface lay
ers of atomic thickness can be exploited to tune the photoemitter propertie
s to the incident light and to enhance the photoelectric yield.