Fine structure of optical spectra of [M2Cu2O3](m)[CuO2](n) crystals

Citation
Gj. Babonas et al., Fine structure of optical spectra of [M2Cu2O3](m)[CuO2](n) crystals, SUPERCOND S, 12(3), 1999, pp. 128-134
Citations number
38
Categorie Soggetti
Apllied Physucs/Condensed Matter/Materiales Science
Journal title
SUPERCONDUCTOR SCIENCE & TECHNOLOGY
ISSN journal
09532048 → ACNP
Volume
12
Issue
3
Year of publication
1999
Pages
128 - 134
Database
ISI
SICI code
0953-2048(199903)12:3<128:FSOOSO>2.0.ZU;2-E
Abstract
The fine structure of the dielectric function in the spectral range 0.5-5.0 eV was studied in the [M2Cu2O3](m) [CuO2](n)-type crystals (where M = Ca, Sr, Y, Bi, rare earth elements) with the min values equal to 1/1,5/7, 7/10 and 9/13. The spectra were compared with those of structural analogues CuO, SrCuO2, Ca2CuO3 and LiCu3O3, containing similar Cu-structural units as wel l as with the spectra of other complex cuprates such as Y-123 and Bi-2212. The qualitative analysis of the spectra allowed one to reveal the correlati on between optical features in the spectra of [M2Cu2O3](m) [CuO2](n), cryst als and electronic excitations in corresponding structural units. On the ba sis of the correlation, the microstructure of various [M2Cu2O3](m)[CuO2](n) crystals was discussed. The general regularities in the fine structure of complex cuprates were described and the specific features for [M2Cu2O3](m)[ CuO2](n), crystals were emphasized.