Directed ortho metalation of ferrocenes. Ring-substituted fulvenes by Nesmeyanov ferrocenylcarbenium ion fragmentation

Authors
Miao, B Tinkl, M Snieckus, V
Citation
B. Miao et al., Directed ortho metalation of ferrocenes. Ring-substituted fulvenes by Nesmeyanov ferrocenylcarbenium ion fragmentation, TETRAHEDR L, 40(13), 1999, pp. 2449-2452
Citations number
27
Categorie Soggetti
Chemistry & Analysis","Organic Chemistry/Polymer Science
Journal title
TETRAHEDRON LETTERS
ISSN journal
00404039 → ACNP
Volume
40
Issue
13
Year of publication
1999
Pages
2449 - 2452
Database
ISI
SICI code
0040-4039(19990326)40:13<2449:DOMOFR>2.0.ZU;2-F
Abstract
A convenient and general synthesis of 6-aryl and 6,6-diaryl ring-functional ized fulvenes from ferrocenyl amide carbinols via a combined Directed ortho Metalation - acid catalyzed fragmentation (Scheme 2) is reported. (C) 1999 Elsevier Science Ltd. All rights reserved.