We investigate the influence of nonequilibrium thermodynamics on cosmologic
al structure formation. In this paper, we consider the collapse of the plan
ar perturbations usually called "Zeldovich pancakes." We have developed for
that purpose a new two-fluid (gas and dark matter) hydrodynamical code, wi
th three different thermodynamical species: electrons, ions, and neutral pa
rticles, T-e not equal T-l not equal T-n. We describe in detail the complex
structure of accretion shock waves. We include several relevant processes
for a low-density, high-temperature collisional plasma: nonequilibrium chem
ical reactions, cooling, shock heating, thermal energy equipartition betwee
n electrons, ions, and neutral particles, and electronic conduction. We fin
d two different regions in the pancake structure: a thermal precursor ahead
of the compression front and an equipartition wave after the compression f
ront, where electron and ion temperatures differ significantly. This comple
x structure may have two interesting consequences: preheating of unshocked
regions in the vicinity of massive X-ray clusters and ion and electron temp
erature differences in the outer regions of X-ray clusters.