The presence of aluminium in the form of different species in natural water
s receives an increasing attention due to better understanding of its bioav
ailability, toxicity and transport mechanism. Recently a number of methods
for fractionating of aluminium have been developed. Most of them are operat
ionally defined, since the validation of what is really measured in real sa
mples is very difficult. This review concerns the specific problems of alum
inium speciation analysis and highlights some important methods used for th
is purpose.