Ni. Kovtyukhova et al., Layer-by-layer assembly of ultrathin composite films from micron-sized graphite oxide sheets and polycations, CHEM MATER, 11(3), 1999, pp. 771-778
Unilamellar colloids of graphite oxide (GO) were prepared from natural grap
hite and were grown as monolayer and multilayer thin films on cationic surf
aces by electrostatic self-assembly. The multilayer films were grown by alt
ernate adsorption of anionic GO sheets and cationic poly(allylamine hydroch
loride) (PAH). The monolayer films consisted of 11-14 Angstrom thick GO she
ets, with lateral dimensions between 150 nm and 9 mu m. Silicon substrates
primed with amine monolayers gave partial GO monolayers, but surfaces prime
d with Al13O4-(OH)(24)(H2O)(12)(7+) ions gave densely tiled films that cove
red approximately 90% of the surface. When alkaline GO colloids were used,
the monolayer assembly process selected the largest sheets (from 900 nm to
9 mu m) from the suspension. In this case, many of the flexible sheets appe
ared folded in AFM images. Multilayer (GO/PAH)(n) films were invariably thi
cker than expected from the individual thicknesses of the sheets and the po
lymer monolayers, and this behavior is also attributed to folding of the sh
eets. Multilayer (GO/PAH), and (GO/polyaniline)(n) films grown between indi
um-tin oxide and Pt electrodes show diodelike behavior, and higher currents
are observed with the conductive polyaniline-containing films. The resisit
ivity of these films is decreased, as expected, by partial reduction of GO
to carbon.