Adsorption and adsorbed species of SO2 during its oxidative removal over pitch-based activated carbon fibers

Adsorption and adsorbed species of SO2 in humid air during its oxidative re moval were studied over pitch-based activated carbon fibers (ACFs) to clari fy the reaction scheme of continuous removal of SO2, influence of reaction variables, and origin of activity enhancement by the calcination in inert a tmosphere. The temperature-programmed desorption of SO2 adsorbed species su ggests that when both oxygen and water were present, the main species on AC F was hydrated SO3 (H2SO4), which desorbed in the form of SO2 around 300 de grees C, and that the presence of both increased the amount of species by o xidizing and hydrating the adsorbed SO2, which desorbed around 60 degrees C without oxidation and 200 degrees C with oxidation but without hydration. The amount of adsorbed H2SO4 over ACF stayed at the same level after 25 h o f reaction by balancing elution and adsorption of H2SO4 to allow the steady removal of SO2, More water enhanced the adsorption of SO2 at the initial s tage but reduced the amount of adsorbed H2SO4 at the steady state, eluting out H2SO4 faster than the adsorption of SO2 to keep more active sites open over ACF at the steady state. Hence, complete removal was achieved. A highe r calcination temperature significantly increased the rate and amount of bo th oxidative and oxidative/hydrating adsorption, explaining the largest act ivity of ACF calcined at 1100 degrees C. The amounts of adsorbed SOz and ev olved CO from OG-20As by calcination at 500-1000 degrees C are well correla ted, indicating that the evolved CO creates an adsorption site on the ACF s urface, A similar but different correlation was obtained among ACFs of diff erent surface areas calcined at different temperatures.