V. Padmavathi et al., Sulfonyl pyrazoles and isoxazoles: Cycloaddition of nitrile imines and nitrile oxides to aryl styryl sulfones, I J CHEM B, 37(12), 1998, pp. 1286-1289
Citations number
15
Categorie Soggetti
Organic Chemistry/Polymer Science
Journal title
INDIAN JOURNAL OF CHEMISTRY SECTION B-ORGANIC CHEMISTRY INCLUDING MEDICINAL CHEMISTRY
Nitrile imines and nitrile oxides by intermolecular cycloaddition reaction
with aryl styryl sulfones 1 lead to the formation of tetrasubstituted pyraz
olines 3 and trisubstituted isoxazolines 6. The 3 and 6 on dehydrogenation
with chloranil in xylene gave pyrazoles 4 and isoxazoles 7. The IR and H-1
NMR spectral data have been used to ascertain the structures of the new com
pounds.