We present an improved quantitative mobility spectrum analysis (i-QMSA) pro
cedure for determining free electron and hole densities and mobilities from
magnetic-field-dependent Hall and resistivity measurements on bulk or laye
red semiconductor samples. The i-QMSA technique is based on a fundamentally
new approach, which optimizes the fit to the conductivity tensor component
s and their slopes by making those adjustments in the mobility spectra that
result in the greatest error reduction. Empirical procedures for manipulat
ing the mobility spectra are also introduced, with the dual purpose of redu
cing the error of the fit and simplifying the shape of the spectra to minim
ize the presence of unphysical artifacts. A fully automated computer implem
entation of the improved QMSA is applied to representative synthetic and re
al data sets involving various semiconductor material systems. These result
s show that, as compared with previous approaches, the presented algorithm
maximizes the information that may be extracted from a given data set, and
is suitable for use as a standard tool in the characterization of semicondu
ctor material and device transport properties. (C) 1998 American Institute
of Physics. [S0021-8979(98)07321-6].