Synthesis of a bifunctional epoxy monomer containing anthracene moiety andproperties of its cured polymer with phenol novolac

Citation
M. Kaji et al., Synthesis of a bifunctional epoxy monomer containing anthracene moiety andproperties of its cured polymer with phenol novolac, J APPL POLY, 72(7), 1999, pp. 953-959
Citations number
10
Categorie Soggetti
Organic Chemistry/Polymer Science","Material Science & Engineering
Journal title
JOURNAL OF APPLIED POLYMER SCIENCE
ISSN journal
00218995 → ACNP
Volume
72
Issue
7
Year of publication
1999
Pages
953 - 959
Database
ISI
SICI code
0021-8995(19990516)72:7<953:SOABEM>2.0.ZU;2-O
Abstract
A new type of epoxy resin containing anthracene moiety in the backbone was synthesized and was confirmed by elemental analysis, infrared spectroscopy, and H-1 nuclear magnetic resonance spectroscopy. Thermal properties of its cured polymer with phenol novolac were examined by thermomechanical, dynam ic mechanical, and thermogravimetric analyses. The cured polymer with pheno l novolac showed higher glass transition temperature (T-g), lower thermal e xpansion, lower moisture absorption, and higher anaerobic char yield at 700 degrees C than a cured polymer having a phenylene group in place of anthra cene moiety. (C) 1999 John Wiley & Sons, Inc.