Erbium doping of silicon has recently emerged as a promising method to tail
or the optical properties of Si towards the achievement of a light emission
at 1.54 mu m. In this paper we will review our recent work on this subject
. In particular a detailed investigation of the non-radiative processes, co
mpeting with the radiative emission of Er in Si will be presented. Among th
ese processes, an Auger de-excitation with the energy released to free carr
iers will be demonstrated to be extremely efficient, with an Auger coeffici
ent C-A similar to 4.4 x 10(-13) cm(3)/s. Moreover, at temperatures above 1
00 K a phonon-assisted back-transfer decay process, characterized by an act
ivation energy of 0.15 eV is seen to set in. This understanding of the phys
ical properties competing with the radiative light emission allowed us to c
ontrol them and obtain efficient room temperature luminescence. Two example
s will be reported. It will be shown that by exciting Er within the depleti
on region of reverse biased p(+)-n(+) Si diodes in the breakdown regime it
is possible to avoid Auger quenching and to achieve high efficiency. Moreov
er, at the switch off of the diode, when the depletion region shrinks, the
excited Er ions become suddenly embedded within the neutral heavily doped r
egion of the device. In this region Auger de-excitation with free carriers
sets in and quenches rapidly the luminescence. This allows to modulate the
light signal at frequencies as high as a few MHz. Furthermore, the introduc
tion of Er within Si nanocrystals is demonstrated to be a promising way to
eliminate back-transfer processes by a widening of the bandgap while mainta
ining the full advantage of the efficient electron-hole mediated excitation
present in Si. These data are presented and future perspective discussed.
(C) 1999 Elsevier Science B.V. All rights reserved.