Morphology of stain-etched porous silicon films was investigated by a non-d
estructive technique, based on reflectance spectrometry: dielectric functio
n profiles were computed by spectral reflectance via a finite difference mo
del, and porosity was deduced by the effective medium approximation. Theore
tical calculations were supported by high-resolution electron microscopy ob
servations. The relations among oxidising species concentration in the etch
ing solution, porosity profile and surface reflectance of the films were in
vestigated. (C) 1999 Elsevier Science B.V. All rights reserved.