Dielectric relaxation and extended rotational diffusion of asymmetric top molecules with account of finite duration of collisions

Authors
Kalmykov, YP Titov, SV
Citation
Yp. Kalmykov et Sv. Titov, Dielectric relaxation and extended rotational diffusion of asymmetric top molecules with account of finite duration of collisions, J MOL STRUC, 479(2-3), 1999, pp. 123-133
Citations number
20
Categorie Soggetti
Physical Chemistry/Chemical Physics
Journal title
JOURNAL OF MOLECULAR STRUCTURE
ISSN journal
00222860 → ACNP
Volume
479
Issue
2-3
Year of publication
1999
Pages
123 - 133
Database
ISI
SICI code
0022-2860(19990427)479:2-3<123:DRAERD>2.0.ZU;2-0
Abstract
The complex dielectric susceptibility of an ensemble of non-interacting pol ar asymmetric top molecules diluted in an inert is calculated in the contex t of the generalized J-diffusion model, which takes into account the finite duration of molecular collisions. The model is applied to calculations of far-infrared absorption spectra of dilute solutions of H2O and D2O molecule s in non-polar solvents. (C) 1999 Elsevier Science B.V. All rights reserved .