Theory of electroabsorption spectroscopy in pyrazine-bridged Ru dimers

A theoretical study of near-IR-vis electroabsorption spectroscopy (Stark ef fect) for the Creutz-Taube ion, a pyrazine-bridged mixed-valence Ru dimer, and for its homovalent +4 analogue is presented. A vibronic model that take s into account correlation effects is considered for the calculation of abs orption line shape profiles, also in the presence of an external static ele ctric field. The model also incorporates the orientation of molecules with respect to the applied field and the polarization of the incident light and accounts for the essential features of the difference spectra that have be en observed experimentally.