A NOVEL ONE-POT CONVERSION OF TETRAACETAL TETRAOXA-CAGES TO AZA-CAGESMEDIATED BY IODOTRIMETHYLSILANE IN ACETONITRILE

Authors
WU HJ CHERN JH
Citation
Hj. Wu et Jh. Chern, A NOVEL ONE-POT CONVERSION OF TETRAACETAL TETRAOXA-CAGES TO AZA-CAGESMEDIATED BY IODOTRIMETHYLSILANE IN ACETONITRILE, Tetrahedron letters, 38(16), 1997, pp. 2887-2890
Citations number
28
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Tetrahedron letters → ACNP
ISSN journal
00404039
Volume
38
Issue
16
Year of publication
1997
Pages
2887 - 2890
Database
ISI
SICI code
0040-4039(1997)38:16<2887:ANOCOT>2.0.ZU;2-A
Abstract
Treatment of the tetraacetal tetraoxa-cages 1a-f with excess of iodotr imethylsilane in acetonitrile at 25 degrees C gave the novel tetraacet al trioxamonoaza-cages 2a-f in 75-80% yields respectively, a novel one -pot conversion of era-cages to ata-cages. (C) 1997 Elsevier Science L td.