Dehalogenation of polychloroarenes with HSiEt3 catalyzed by an homogeneousrhodium-triphenylphosphine system

Authors
Esteruelas, MA Herrero, J Lopez, FM Martin, M Oro, LA
Citation
Ma. Esteruelas et al., Dehalogenation of polychloroarenes with HSiEt3 catalyzed by an homogeneousrhodium-triphenylphosphine system, ORGANOMETAL, 18(6), 1999, pp. 1110-1112
Citations number
32
Categorie Soggetti
Organic Chemistry/Polymer Science
Journal title
ORGANOMETALLICS
ISSN journal
02767333 → ACNP
Volume
18
Issue
6
Year of publication
1999
Pages
1110 - 1112
Database
ISI
SICI code
0276-7333(19990315)18:6<1110:DOPWHC>2.0.ZU;2-8
Abstract
In the presence of HSiEt3, the rhodium system formed by addition, of PPh3 t o [Rh(mu-Cl)(COE)(2)](2) (COE = cyclooctene) simultaneously catalyzes the d ehalogenation of polychloroarenes and the formation of Et3SiCl.