Tellurium donors in GaP have been ionized by phonon-assisted tunneling
in the electric field of pulsed far-infrared laser radiation. In resp
onse to the laser pulse a photoconductive signal has been detected wit
h a fast component that follows in time the laser pulse and a slow com
ponent that rises after the irradiation has ceased and finally exponen
tially decays with a strongly temperature-dependent time constant vary
ing from several microseconds to milliseconds. It is shown that this t
emporal structure of the signal is due to a storage of carriers in the
valley-orbit split 1s(E) shallow donor state. Observation of far-infr
ared to mid-infrared up-conversion demonstrates that the final step of
cascade recombination is achieved by radiative transitions.