Growth al step edges by the addition of single adatoms has been studie
d using scanning tunneling microscopy (STM). It is shown that the use
of empty-state instead of filled-state STM images enables the assessme
nt of the binding sites of single adatoms at step edges. We describe a
ll different step edge configurations obtained by subsequently stickin
g adatoms to these step edges. Adatom diffusion along step edges as we
ll as the dimerization of adatoms at a step edge are also demonstrated
. Finally, the creation of single dimer vacancies at step edges is dis
cussed.