We report for the first time on temperature-dependent spectroscopy of charg
e excitations in FeSi single crystals probed with a low-temperature STM bet
ween 4 and 300 K. Below approximate to 200 K, two peaks start to emerge in
the differential conductance (dI/dV) on either side of the Fermi level, whi
ch grow with decreasing temperature and are separated by a (pseudo-)gap of
approximate to 50 meV. We ascribe this change in the tunneling spectra to t
he formation of quasiparticle density of states caused by d-electron correl
ations. We find good agreement with photoemission spectroscopy since both m
ethods are sensitive to the correlated d-electron density of states (DOS).
Our results are also consistent with optical reflectivity data and Raman sp
ectroscopy which, in contrast, are sensitive to the conduction (c) electron
DOS. (C) 1999 Elsevier Science B.V. All rights reserved.