SLOW DYNAMICS AND INSTABILITY IN BAZNF4

The low-frequency dynamics of BaZnF4 has been investigated in the temp erature range T=300-15 K. The dispersion surfaces at room temperature display a deep valley located along the (0.5, zeta, 0.5) zone-boundary line. This valley becomes deeper when T decreases, showing a soft-mod e behavior. In addition a new depression appears at low-temperature al ong the (xi, 0.5, 0.5) line, corresponding to an incipient instability toward an incommensurate phase. A symmetry analysis of the vibration spectrum including the compatibility relations between the different i rreducible representations, is presented. The soft-mode symmetry is de termined as belonging to the I-1 representation. The present results a re compared to previous Raman and x-ray investigations performed on th is compound.