THERMAL AND ELECTROPHYSICAL PROPERTIES OF OLIGOMERIC SALTS OF M-CARBORANEDICARBOXYLIC ACID

Authors
SERGEEV VA ASKADSKII AA SURIKOVA MA KAZANTSEVA VV BEKASOVA NI BARYSHNIKOVA EA
Citation
Va. Sergeev et al., THERMAL AND ELECTROPHYSICAL PROPERTIES OF OLIGOMERIC SALTS OF M-CARBORANEDICARBOXYLIC ACID, Vysokomolekularnye soedinenia. Seria A, 39(2), 1997, pp. 334-337
Citations number
9
Categorie Soggetti
Polymer Sciences
Journal title
Vysokomolekularnye soedinenia. Seria A → ACNP
ISSN journal
05075475
Volume
39
Issue
2
Year of publication
1997
Pages
334 - 337
Database
ISI
SICI code
0507-5475(1997)39:2<334:TAEPOO>2.0.ZU;2-G
Abstract
A relationship between the thermal and electrophysical properties of t he oligosalts of m-carboranedicarboxylic acid [-OOC-CB10H10C-COO-Mt(2)](n) (Mt = Cu, Mg, Ca, Zn, Cd, Ph) was established. The electric cond uctivity of the salts heat treated at 500 degrees C increases by 3-9 d ecimal orders; after pyrolysis at 900 degrees C, the conductivity incr eases by 6-11 orders. Even after three years of storage, the conductiv ity of the pyrolysis products remains 3-9 orders higher than that of t he initial oligosalts.