Monte Carlo simulations of formamide-N,N-dimethylformamide mixtures in the
whole range of compositions were carried out at 298 K. Structural propertie
s were investigated by calculating the atom-atom spatial distribution funct
ions, generalized spatial distribution functions, concentrations of closed
cycles of H-bonds, and other properties of the system of hydrogen bonds. It
was found that local spatial regions with the structure of pure components
are conserved in a wide range of concentrations. The regularities of manif
estation of solvophobic effects have been established.