Oxidation with the "H2O2-manganese(IV) complex carboxylic acid" reagent - 1. Oxidation of saturated hydrocarbons with peroxy acids and hydrogen peroxide
Gb. Shul'Pin et Jr. Lindsay-smith, Oxidation with the "H2O2-manganese(IV) complex carboxylic acid" reagent - 1. Oxidation of saturated hydrocarbons with peroxy acids and hydrogen peroxide, RUSS CHEM B, 47(12), 1998, pp. 2379-2386
The complex [LMnIV(O)(3)(MnL)-L-IV](PF6)(2) (1), where L is 1,4,7-trimethyl
-1,4,7-triazacyclononane, catalyzes a highly efficient stereoselective oxyg
enation of saturated hydrocarbons in the presence of H2O2. A carboxylic aci
d is an obligatory component of the reaction mixture, while acetonitrile or
acetone can be used as solvent. The reaction occurs, forming alkyl hydrope
roxide, ketone, and alcohol. Substitution at the tertiary cart,on atom proc
eeds more easily than that at the secondary carbon atom, whereas primary C-
H bonds are rather inactive. Oxidation of alkanes and alcohols with peroxy
acids catalyzed by complex 1 occurs with lower efficiency.