The formation of nitroxyl radicals in reactions of dimethyldioxirane with 2,2,6,6-tetramethylpiperidine and 2,2,5,5-tetramethyl-3-imidazoline-3-oxid derivatives

Authors
Kabal'nova, NN Grabovsky, SA Shishlov, NM Shereshovets, VV Volodarskii, LB Tolstikov, GA
Citation
Nn. Kabal'Nova et al., The formation of nitroxyl radicals in reactions of dimethyldioxirane with 2,2,6,6-tetramethylpiperidine and 2,2,5,5-tetramethyl-3-imidazoline-3-oxid derivatives, RUSS CHEM B, 47(12), 1998, pp. 2419-2421
Citations number
17
Categorie Soggetti
Chemistry
Journal title
RUSSIAN CHEMICAL BULLETIN
ISSN journal
10665285 → ACNP
Volume
47
Issue
12
Year of publication
1998
Pages
2419 - 2421
Database
ISI
SICI code
1066-5285(199812)47:12<2419:TFONRI>2.0.ZU;2-Z
Abstract
The oxidation of secondary and tertiary amines, derivatives of 2,2,6,6-tetr amethyipiperidine and 2,2,5,5-tetramethyl-3-imidazoline-3-oxide, by dimethy ldioxirane results in the formation of nitroxyl radicals, which induce the decomposition of dimethyldioxirane. Chemiluminescence in the IR and visible regions during the reaction of dimethyldioxirane with 2,2,6,6-tetramethyl- 4-hydroxypiperidine-1-oxyl was observed.