Reactions of 1,4-dioxa-2-silacyclohexanes with acetyl chloride

Authors
Zhdanov, AA Makarova, LI Sergienko, NV
Citation
Aa. Zhdanov et al., Reactions of 1,4-dioxa-2-silacyclohexanes with acetyl chloride, RUSS CHEM B, 47(12), 1998, pp. 2445-2447
Citations number
5
Categorie Soggetti
Chemistry
Journal title
RUSSIAN CHEMICAL BULLETIN
ISSN journal
10665285 → ACNP
Volume
47
Issue
12
Year of publication
1998
Pages
2445 - 2447
Database
ISI
SICI code
1066-5285(199812)47:12<2445:RO1WAC>2.0.ZU;2-#
Abstract
The reactions of 1,4-dioxa-2-silacyclohexanes with acetyl chloride lead to the cleavage of the Si-O bond to form chlorotriorganosilanes containing the acetoxy group in the organic radical at the silicon atom. Hydrolysis of th ese chlorosilanes affords bis(acetoxyalkoxy(aryloxy)methyl)disiloxanes, whi le the reactions with cage copper sodium phenylsiloxane give dodecaphenyl[d odeca(acetoxyorganodimethylsilyloxy)]cyclododecasiloxanes.