A new class of insulating and passivating layers on gallium antimonide
has been prepared by means of an electrochemical process. In previous
work we used this new process of fabrication of passivating and insul
ating layers for gating devices made from GaSb/InAs/GaSb nanostructure
s (Chen Y et al 1994 Superlatt. Microstruct. 15 41 and Chen Y 1995 PhD
Thesis Hertford College, Oxford, UK). In this publication we describe
the effects of the electrochemical process leading to an improvement
of the photoluminescence (PL) after the growth of the passivating laye
r on GaSb. The PL measurements on (100), (111A) and (111B) GaSb substr
ates and on GaSb epilayers grown by MOVPE on GaAs indicate significant
improvement of the PL intensity even after 12 months. Similar results
have been observed on InGaSb/GaSb superlattice structures.