THERMODYNAMIC BASIS FOR CHARGED-PARTICLES TRANSPORT IN VISCOELASTIC FLUIDS

Citation
A. Estradaflores et al., THERMODYNAMIC BASIS FOR CHARGED-PARTICLES TRANSPORT IN VISCOELASTIC FLUIDS, The Journal of chemical physics, 107(22), 1997, pp. 9542-9548
Citations number
30
ISSN journal
00219606
Volume
107
Issue
22
Year of publication
1997
Pages
9542 - 9548
Database
ISI
SICI code
0021-9606(1997)107:22<9542:TBFCTI>2.0.ZU;2-5
Abstract
A calculation for the generalized longitudinal stress modulus and elec tric conductivity in an ionic-viscoelastic medium is presented. The sy stem is described within the framework of extended irreversible thermo dynamics in terms of the regular conserved variables and of an additio nal set of independent variables consisting of the stress tensor, its trace, and the electric flux. Using the standard procedure, we derive the time evolution equations for the additional variables. These equat ions are used to obtain general wave vector and frequency dependent ex pressions for measurable properties of the system. We obtain for the l inear case results that have not been derived previously in the litera ture. (C) 1997 American Institute of Physics.