N,PI-CONJUGATION IN N-METHYLVINYLAMINE - A PHOTOELECTRON SPECTROSCOPIC STUDY

Authors
FANG JY SIM CW MOK CY HUANG HH NOVAK I
Citation
Jy. Fang et al., N,PI-CONJUGATION IN N-METHYLVINYLAMINE - A PHOTOELECTRON SPECTROSCOPIC STUDY, Perkin transactions. 2, (8), 1995, pp. 1625-1627
Citations number
22
Categorie Soggetti
Chemistry Physical","Chemistry Inorganic & Nuclear
Journal title
Perkin transactions. 2 → ACNP
ISSN journal
03009580
Issue
8
Year of publication
1995
Pages
1625 - 1627
Database
ISI
SICI code
0300-9580(1995):8<1625:NIN-AP>2.0.ZU;2-H
Abstract
The unstable species N-methylvinylamine was prepared by-the thermal de composition of gaseous 2-methylaziridine in a flow system and its UV p hotoelectron spectrum was recorded. The first two bands were observed at 8.00 and 11.00 eV. The methyl substituent shows the effect of reduc ing the degree of conjugation between the n(N) and pi(CC) orbitals, as revealed by a comparison with the spectrum of the parent compound vin ylamine.