STRUCTURE OF AMORPHOUS PLATINUM URIDINE GREEN SULFATE BY AWAXS AND EXAFS

Citation
R. Serimaa et al., STRUCTURE OF AMORPHOUS PLATINUM URIDINE GREEN SULFATE BY AWAXS AND EXAFS, Inorganic chemistry, 36(24), 1997, pp. 5574-5579
Citations number
55
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
ISSN journal
00201669
Volume
36
Issue
24
Year of publication
1997
Pages
5574 - 5579
Database
ISI
SICI code
0020-1669(1997)36:24<5574:SOAPUG>2.0.ZU;2-0
Abstract
Amorphous platinum uridine green sulfate was studied using anomalous w ide-angle X-ray scattering and X-ray absorption techniques. Experiment s were made with synchrotron radiation in the vicinity of the Pt L-III absorption edge. The experimental results agree with a mixture model where the major components are mono-and dinuclear Pt complexes. The in tramolecular Pt-Pt distance of 3 Angstrom and the shortest intermolecu lar Pt-PI distances of 5.1 and 7.3 Angstrom were determined from the a pproximative regularized Pt-Pt partial, radial distribution function. The shortest average Pt-O and Pt-N distance of 2.03 Angstrom was obtai ned from the EXAFS data.