ETHYLENE POLYMERIZATION WITH CP2ZRCL2 SUPPORTED ON DEALUMINATED Y-ZEOLITE

Citation
Mdv. Marques et al., ETHYLENE POLYMERIZATION WITH CP2ZRCL2 SUPPORTED ON DEALUMINATED Y-ZEOLITE, Polymer bulletin, 39(5), 1997, pp. 567-571
Citations number
8
Journal title
ISSN journal
01700839
Volume
39
Issue
5
Year of publication
1997
Pages
567 - 571
Database
ISI
SICI code
0170-0839(1997)39:5<567:EPWCSO>2.0.ZU;2-V
Abstract
Y zeolites with different aluminium contents obtained by dealumination with ammonium hexafluorosilicate were evaluated as supports for bis(c yclopentadienyl)-zirconium dichloride catalysts. The activities of the supported and homogeneous systems were compared for ethylene polymeri zation. The most active heterogeneous catalyst was the one supported o n the zeolite with the higher Si/Al ratio and external area.